S‐Adenosyl‐L‐(1‐ 14 C)‐homocysteine | Zendy

Thomas H. Jeanette | Zendy; Montgomery John A. | Zendy

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S‐Adenosyl‐L‐(1‐ 14 C)‐homocysteine

Author(s) -

Thomas H. Jeanette,

Montgomery John A.

Publication year - 1987

Publication title -

journal of labelled compounds and radiopharmaceuticals

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.432

H-Index - 47

eISSN - 1099-1344

pISSN - 0362-4803

DOI - 10.1002/jlcr.2580241215

Subject(s) - chemistry , homocysteine , salt (chemistry) , sodium , liquid ammonia , ammonia , plasma homocysteine , sodium salt , medicinal chemistry , nuclear chemistry , inorganic chemistry , organic chemistry , biochemistry

S‐Adenosyl‐L‐(1‐ 14 C)‐homocysteine ( 3 ) was prepared from commercially available L‐(1‐ 14 C)‐methionine ( 1 ) by conversion first to S‐benzyl‐L‐(1‐ 14 C)‐homocysteine ( 2 ), which upon treatment with sodium in liquid ammonia gave the disodium salt of L‐(1‐ 14 C)‐homocysteine. Reaction of this sodium salt with 5′‐O‐tosyladenosine gave 3 .

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