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New realistic approach of the kinetics in fast labelling procedures
Author(s) -
Mertens J.,
Callaerts A.,
Vanryckeghem W.
Publication year - 1987
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580240517
Subject(s) - chemistry , labelling , isothermal process , kinetics , kinetic energy , transient (computer programming) , thermodynamics , process (computing) , chemical kinetics , transformation (genetics) , biological system , biochemistry , physics , quantum mechanics , computer science , gene , operating system , biology
A real kinetic approach of fast labelling reactions is obtained by introducing a corrected reaction time τ which takes into account the temperature rise process of the reaction solution. τ is obtained by transformation of transient temperature data to isothermal conditions at a preset temperature. Experimental data obtained for 123 I‐radioiodination of ortho‐iodohippuric acid fit completely with the theory.