Premium
Stereochemistry of reductive dehalogenation with deuterium gas
Author(s) -
Kaspersen Frans M.,
Sperling Eric M.
Publication year - 1986
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580230605
Subject(s) - chemistry , stereospecificity , halogenation , stereoselectivity , deuterium , reductive dechlorination , reductive elimination , stereochemistry , catalysis , medicinal chemistry , organic chemistry , biodegradation , quantum mechanics , physics
The stereochemistry of reductive debromination and deiodination of 4‐haloprolines and 2‐ or 7‐bromo‐cholesterols with 2 H 2 catalyzed by Pd was investigated using 2 H NMR. The reactions are stereoselective but not stereospecific.