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1,3,5‐Trinitroso‐ and 1,3,5‐trinitrohexahydro‐1,3,5‐triazine‐ 2 H 6
Author(s) -
Boyer Joseph H.,
Kumar G.
Publication year - 1985
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580220102
Subject(s) - chemistry , alkoxide , hydrogen peroxide , nitric acid , triazine , potassium , medicinal chemistry , 1,3,5 triazine , hydrogen , nuclear chemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Perdeuteration of 1,3,5‐trinitrosohexahydro‐1,3,5‐triazine was brought about by treatment with potassium alkoxide in CH 3 O 2 H(99.5%). The important high energy compound, 1,3,5‐trinitrohexahydro‐1,3,5‐ triazine (RDX), was obtained in its perdeuterated modification (>99% 2 H) by oxidation of the perdeuterated trinitrosamine with a mixture of nitric acid (100%) and hydrogen peroxide (30%).