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Aminozucker‐Derivate des Ferrocens und Ruthenocens ‐ Synthese und Markierung mit 14 C und 103 Ru
Author(s) -
Schneider Michael,
Wenzel Martin
Publication year - 1981
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580180303
Subject(s) - chemistry , aldehyde , yield (engineering) , ruthenocene , stereochemistry , medicinal chemistry , metallocene , organic chemistry , catalysis , materials science , polymer , metallurgy , polymerization
Glucosamine, galactosamine and mannosamine react with ferrocene‐ or ruthenocene‐carbaldehyde, respectively to yield the corresponding Schiff's bases, which are reduced at the CN‐bond and at the aldehyde function of the sugar moity. With 14 C‐labelled amino‐sugars or 103 Ru‐labelled ruthenocene‐carbaldehyde the labelled aminohexite compounds of the metallocenes are synthesized.