Synthesis of  N ‐methylmorpholine  N ‐( 17 O‐oxide) and  N ‐methylmorpholine   15 N ‐( 17 O‐oxide) | Zendy

Opietnik Martina | Zendy; Potthast Antje | Zendy; Kitaoka Takuya | Zendy; Rosenau Thomas | Zendy

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Synthesis of N ‐methylmorpholine N ‐( 17 O‐oxide) and N ‐methylmorpholine 15 N ‐( 17 O‐oxide)

Author(s) -

Opietnik Martina,

Potthast Antje,

Kitaoka Takuya,

Rosenau Thomas

Publication year - 2010

Publication title -

journal of labelled compounds and radiopharmaceuticals

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.432

H-Index - 47

eISSN - 1099-1344

pISSN - 0362-4803

DOI - 10.1002/jlcr.1708

Subject(s) - chemistry , hydrogen peroxide , oxide , electrolysis , inorganic chemistry , nuclear chemistry , organic chemistry , electrolyte , electrode

N ‐Methylmorpholine N ‐( 17 O‐oxide) and N ‐methylmorpholine 15 N ‐( 17 O‐oxide) were prepared from N ‐methylmorpholine and 15 N ‐methylmorpholine by oxidation with H 2 17 O 2 . The facile one‐pot procedure provided yields of 82 and 76%, respectively. The labeled hydrogen peroxide was obtained by electrolysis of H 2 17 O followed by autoxidation of 2‐ethylanthraquinol with the molecular oxygen 17 O 2 generated. The compounds serve for mechanistic studies into gold nanoparticle generation in NMMO solution. Copyright © 2009 John Wiley & Sons, Ltd.

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