Probing the regioselective  C ‐deuteriation of lithium enolates derived from 2‐methyl‐tetralone in the presence of substituted tertiary amines | Zendy

Begum Mothia | Zendy; Chavda Sameer | Zendy; Coumbarides Gregory S. | Zendy; Dingan Marco | Zendy; Eames Jason | Zendy; Suggate Michael J. | Zendy; Weerasooriya Neluka | Zendy

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Probing the regioselective C ‐deuteriation of lithium enolates derived from 2‐methyl‐tetralone in the presence of substituted tertiary amines

Author(s) -

Begum Mothia,

Chavda Sameer,

Coumbarides Gregory S.,

Dingan Marco,

Eames Jason,

Suggate Michael J.,

Weerasooriya Neluka

Publication year - 2006

Publication title -

journal of labelled compounds and radiopharmaceuticals

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.432

H-Index - 47

eISSN - 1099-1344

pISSN - 0362-4803

DOI - 10.1002/jlcr.1089

Subject(s) - chemistry , lithium (medication) , tetralone , regioselectivity , tertiary amine , tetralones , organic chemistry , stereochemistry , catalysis , medicine , endocrinology

Results are reported on the regioselective C ‐deuteriation of 2‐methyl‐tetralone using a series of D ‐sources and tertiary amines as potential mediators. The results presented further aid the understanding of kinetic deuteriation of both ‘base‐containing’ and ‘base‐free’ enolates. Copyright © 2006 John Wiley & Sons, Ltd.

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