An improvement to the synthesis of deuterated meso‐tetraphenylporphyrins | Zendy

Asano Motoko S. | Zendy; Abe Hiroshi | Zendy; Kaizu Youkoh | Zendy

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An improvement to the synthesis of deuterated meso‐tetraphenylporphyrins

Author(s) -

Asano Motoko S.,

Abe Hiroshi,

Kaizu Youkoh

Publication year - 2006

Publication title -

journal of labelled compounds and radiopharmaceuticals

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.432

H-Index - 47

eISSN - 1099-1344

pISSN - 0362-4803

DOI - 10.1002/jlcr.1077

Subject(s) - chemistry , deuterium , porphyrin , pyrrole , labelling , chemical synthesis , relaxation (psychology) , photochemistry , combinatorial chemistry , organic chemistry , biochemistry , physics , quantum mechanics , in vitro , psychology , social psychology

An improved method for the synthesis of deuterated tetraphenylporphyrins (TPPs) is reported. In this method, deuterium labelling at the pyrrole– β ‐position is increased to more than 95 at%. TPP is the most widely used synthetic porphyrin and high deuterium incorporation is essential for spectroscopic studies and kinetic studies involving relaxation processes. Copyright © 2006 John Wiley & Sons, Ltd.

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