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Some Reactions of the Chloromethyl trans ‐β‐Styryl Sulfone Carbanion
Author(s) -
Ma̧kosza Mieczyslaw,
Krylova Irina
Publication year - 1997
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199719971122
Subject(s) - carbanion , sulfone , chemistry , benzaldehyde , acrylonitrile , catalysis , medicinal chemistry , polymer chemistry , organic chemistry , polymer , copolymer
The chloromethyl trans ‐β‐styryl sulfone carbanion reacts with benzaldehyde and acrylonitrile under phase‐transfer catalysis conditions to give 2‐phenyl‐3‐( trans ‐β‐styrylsulfonyl)oxirane and bis(2‐cyanoethyl)chloromethyl trans ‐β‐styryl sulfone, respectively, and with nitroarenes to form the products of vicarious nucleophilic substitution of hydrogen.