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An Improved Synthesis of 1,3,3‐Trimethyl‐2‐azabicyclo[2.2.2]octane and Its Nitroxyl Radical Product, a Rigid Analogue of TEMPO
Author(s) -
Bakunov Stanislav,
Tkachev Alexey
Publication year - 1997
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199719970740
Subject(s) - nitroxyl , chemistry , yield (engineering) , octane , product (mathematics) , organic chemistry , thermodynamics , physics , geometry , mathematics
A new synthetic approach for the production of isoquinuclidine 6 from dipentene ( rac ‐limonene, 1 ) is described. The nitroxyl 5 , a rigid analogue of TEMPO, has been prepared from 6 in 87% yield.