Pheromone Synthesis, CLXXXI . Synthesis of the Racemate and the Enantiomers of ( Z )‐7,15‐Hexadecadien‐4‐olide, the Sex Pheromone of the Yellowish Elongate Chafer,  Heptophylla picea | Zendy

Nakayama Tôru | Zendy; Mori Kenji | Zendy

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Pheromone Synthesis, CLXXXI . Synthesis of the Racemate and the Enantiomers of ( Z )‐7,15‐Hexadecadien‐4‐olide, the Sex Pheromone of the Yellowish Elongate Chafer, Heptophylla picea

Author(s) -

Nakayama Tôru,

Mori Kenji

Publication year - 1997

Publication title -

liebigs annalen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0947-3440

DOI - 10.1002/jlac.199719970508

Subject(s) - pheromone , enantiomer , sex pheromone , chemistry , stereochemistry , enantioselective synthesis , lipase , botany , catalysis , organic chemistry , biology , enzyme

(4 R ,7 Z )‐7,15‐Hexadecadien‐4‐olide ( 1 ), the female‐produced sex pheromone of the yellowish elongate chafer ( Heptophylla picea ), was synthesized by lipase‐catalyzed resolution of (±)‐ 10 . The racemate and the opposite ( S )‐enantiomer of the pheromone were also synthesized. Both ( R )‐ 1 and (±)‐ 1 showed the pheromone activity.

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