Bromine Complexes of Ethylene and Cyclopropene: Matrix‐IR‐Spectroscopic Identification, Photochemical Reactions, Ab Initio Studies | Zendy

Maier Günther | Zendy; Senger Stefan | Zendy

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Bromine Complexes of Ethylene and Cyclopropene: Matrix‐IR‐Spectroscopic Identification, Photochemical Reactions, Ab Initio Studies

Author(s) -

Maier Günther,

Senger Stefan

Publication year - 1997

Publication title -

liebigs annalen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0947-3440

DOI - 10.1002/jlac.199719970208

Subject(s) - cyclopropene , chemistry , bromine , ethylene , ab initio , photochemistry , matrix isolation , ab initio quantum chemistry methods , computational chemistry , matrix (chemical analysis) , infrared spectroscopy , organic chemistry , catalysis , molecule , chromatography

The matrix‐isolated ethylene–bromine complex ( 1 ) and the cyclopropene–bromine complex ( 8 ) have been chosen to examine which ab initio method (MP2 or BLYP) is more suitable to calculate the IR spectra and structures of π complexes. In addition the photochemistry of 1 and 8 has been investigated and the mechanism of the photochemically induced reactions is discussed.

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