Synthesis, Resolution and Crystal Structure of a New Optically Active Nitroxide Radical | Zendy

Benfaremo Nicholas | Zendy; Steenbock Marco | Zendy; Klapper Markus | Zendy; Müllen Klaus | Zendy; Enkelmann Volker | Zendy; Cabrera Karin | Zendy

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Synthesis, Resolution and Crystal Structure of a New Optically Active Nitroxide Radical

Author(s) -

Benfaremo Nicholas,

Steenbock Marco,

Klapper Markus,

Müllen Klaus,

Enkelmann Volker,

Cabrera Karin

Publication year - 1996

Publication title -

liebigs annalen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0947-3440

DOI - 10.1002/jlac.199619960912

Subject(s) - nitroxide mediated radical polymerization , chemistry , enantiomer , resolution (logic) , optically active , crystal structure , stereochemistry , crystallography , organic chemistry , radical polymerization , polymer , artificial intelligence , computer science , copolymer

The synthesis of the readily available racemate of the nitroxide radical 5 is described. The product exhibits exclusively the trans configuration. The cis product was not obtained. Optically pure enantiomers of 5 were isolated in gram quantities by chiral HPLC. Thus, separation of the enantiomers of a nitroxide radical was achieved for the first time. The structure of 5 was proven by a single‐crystal diffraction study.

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