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Diastereo‐ and Enantioselective Diels‐Alder Reactions of 2‐Amino‐1,3‐dienes
Author(s) -
Enders Dieter,
Meyer Oliver
Publication year - 1996
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199619960702
Subject(s) - enantioselective synthesis , chemistry , cyclopropanation , cycloaddition , stereoselectivity , diels–alder reaction , conjugated system , organic chemistry , scope (computer science) , catalysis , polymer , computer science , programming language
The employment of 2‐amino substituted 1,3‐dienes in cycloaddition reactions has recently extended the scope of Diels‐Alder methodologies. In this review, the preparation of a variety of 2‐amino‐1,3‐dienes is presented, and the use of these cross conjugated enamines in normal as well as hetero Diels‐Alder reactions is depicted. Diastereo‐ and enantioselective variations show new aspects for the preparation of cyclic carbonyl compounds in a highly stereoselective fashion. Further cyclisation reactions e.g. cyclopropanation reactions are also considered in this account.