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Synthesis of Mono‐ and Sesquiterpenoids, XXV. Synthesis of (6 R *,7 R *)‐7‐Hydroxy‐6,11‐cyclofarnes‐3(15)‐en‐2‐one, the Racemate of the Antibacterial Sesquiterpene from Premna oligotricha , and Its (6 R *,7 S *) Isomer
Author(s) -
Yajima Arata,
Takikawa Hirosato,
Mori Kenji
Publication year - 1996
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199619960606
Subject(s) - sesquiterpene , chemistry , antibacterial activity , stereochemistry , bacteria , biology , genetics
The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)‐ 1 and (±)‐ 2 .
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