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Synthesis and Crystal Structure of a Bis[6.3.3]propellane
Author(s) -
Jamrozik Janusz,
Żeslawski Wojeciech,
Grochowski Jacek,
Serda Pawel,
Dauter Zbigniew
Publication year - 1996
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199619960416
Subject(s) - propellane , chemistry , dihedral angle , derivative (finance) , crystal structure , tetrahydrofuran , molecule , crystallography , stereochemistry , bicyclic molecule , organic chemistry , hydrogen bond , solvent , financial economics , economics
The bis[6.3.3]propellane 6 derivative of 2,2′,6,6′‐tetramethylbiphenyl was, in the final stage, synthesized by dehydration, of octaalcohol 5 . X‐ray structure analysis revealed the highly symmetric shape of the molecule and disordered oxygen atoms in the tetrahydrofuran rings. The dihedral angle between LSQ phenyl planes is 62.6(1)°.