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Novel Tetrathiafulvalenes Based on Macrocyclic Thioethers
Author(s) -
Wagner Michael,
Zeltner Stephan,
Olk RuthMaria
Publication year - 1996
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.199619960415
Subject(s) - chemistry , intramolecular force , combinatorial chemistry , polymer chemistry , stereochemistry
Macrocyclic polythioethers ( 7 – 10 , 17 ) and the oxothioether 21 were synthesized by starting with the key compound 4,5‐bis(benzoylthio)‐1,3‐dithiole‐2‐thione ( 1 ). Intramolecular phosphite coupling reactions yielded symmetrically and unsymmetrically substituted tetrathiafulvalenes 11 – 14 and 22 , respectively.