Synthesis of Sphingosine Relatives, XVII!  Synthesis of (2 S ,2'  R ,3 R ,3'  E ,4 E ,8 E )‐1‐ O ‐(β‐ D ‐Glucopyranosyl)‐ N ‐(2'‐hydroxy‐3'‐octadecenoyl)‐9‐methyl‐4,8‐sphingadienine (Pen II), the Major Cerebroside Isolated from  Penicillium funiculosum  as the Fruiting‐Inducer Against  Schizophyllum commune | Zendy

Mori Kenji | Zendy; Uenishi Keiji | Zendy

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Synthesis of Sphingosine Relatives, XVII! Synthesis of (2 S ,2' R ,3 R ,3' E ,4 E ,8 E )‐1‐ O ‐(β‐ D ‐Glucopyranosyl)‐ N ‐(2'‐hydroxy‐3'‐octadecenoyl)‐9‐methyl‐4,8‐sphingadienine (Pen II), the Major Cerebroside Isolated from Penicillium funiculosum as the Fruiting‐Inducer Against Schizophyllum commune

Author(s) -

Mori Kenji,

Uenishi Keiji

Publication year - 1996

Publication title -

liebigs annalen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0947-3440

DOI - 10.1002/jlac.199619960102

Subject(s) - chemistry , stereochemistry , sphingosine , schizophyllum commune , serine , biochemistry , enzyme , receptor

Pen II [(2 S ,2' R ,3 R ,3' E ,4 E ,8 E )‐1‐ O ‐(β‐ D ‐glucopyranosyl)‐ N ‐(2'‐hydroxy‐3'‐octadecenoyl)‐9‐methyl‐4,8‐sphingadienine], the major component of the cerebrosides isolated from Penicillium funiculosum A‐1 as the fruiting inducer against Schizophyllum commune , was synthesized by starting from D ‐glucose, L ‐serine, (2 R ,3 E )‐2‐( tert ‐butyldiphenylsilyloxy)‐3‐octadecenoic acid, and ( E )‐6‐methyl‐5‐pentadecen‐1‐yne.

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