New anthranilic and methylsulfonylpropenoic acid amides from thai  Glycosmis  species | Zendy

Hofer Otmar | Zendy; Zechner Gabriela | Zendy; Vajrodaya Srunya | Zendy; Lutz Gerda | Zendy; Greger Harald | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

New anthranilic and methylsulfonylpropenoic acid amides from thai Glycosmis species

Author(s) -

Hofer Otmar,

Zechner Gabriela,

Vajrodaya Srunya,

Lutz Gerda,

Greger Harald

Publication year - 1995

Publication title -

liebigs annalen

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0947-3440

DOI - 10.1002/jlac.1995199510250

Subject(s) - phenethylamine , chemistry , anthranilic acid , residue (chemistry) , amine gas treating , stereochemistry , mass spectrometry , organic chemistry , chromatography

Five new methylsulfonylpropenamides were isolated from different Glycosmis species collected in Thailand. Four of these derivatives contain 4‐geranyloxy‐3‐hydroxy‐substituted phenethylamine moieties, Sakerine ( 1 ) has a simple geranyloxy side chain; sakerone ( 2 ), sakerol ( 3 ), and dihydroisosakerol ( 4 ) are characterized by different states of oxidation in the geranyloxy residue. Methylgerambullal ( 5 ) contains a 4‐geranyloxy‐substituted phenethylamine unit with a terminal formyl group. Two additional amides, doisuthine ( 6 ) and methoxydoisuthine ( 7 ), exhibit the structures of N ‐methylanthranilic acid amides with phenethylamine and p ‐methoxyphenethylamine as amine components. All structures were elucidated by IR, UV, 1 H‐, 13 C‐, 2D‐NMR spectroscopy, mass spectrometry, and CD spectroscopy.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research