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Synthetic microbial chemistry, XXVIII. Synthesis and absolute configuration of (−)‐koninginin A
Author(s) -
Mori Kenji,
Abe Kaoru
Publication year - 1995
Publication title -
liebigs annalen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0947-3440
DOI - 10.1002/jlac.1995199506135
Subject(s) - chemistry , absolute configuration , absolute (philosophy) , organic chemistry , epistemology , philosophy
The absolute configuration of the microbial metabolite (−)‐koninginin A (2‐hexyloctahydro‐2 H ‐3,9a‐epoxy‐1‐benzoxe‐pine‐6,9‐diol, 1 ) is shown to have the configuration 2 S ,3 S ,6 R ,9 S by its synthesis employing the Sharpless asymmetric dihydroxylation.