Synthesis of New Terpene Skeletons by Chemical Cyclization of Epoxy Olefins | Zendy

Mori Kenji | Zendy; Aki Shinji | Zendy; Kido Masaru | Zendy

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Synthesis of New Terpene Skeletons by Chemical Cyclization of Epoxy Olefins

Author(s) -

Mori Kenji,

Aki Shinji,

Kido Masaru

Publication year - 1994

Publication title -

liebigs annalen der chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0170-2041

DOI - 10.1002/jlac.199419940402

Subject(s) - chemistry , epoxy , derivative (finance) , terpene , tin , indene , chloride , olefin fiber , catalysis , organic chemistry , epoxide , titanium , financial economics , economics

Tin(IV) chloride catalyzed cyclization of the epoxy olefin (±)‐ 7 gave the octahydroazulene derivative (±)‐ 9 , the structure of which was solved by X‐ray analysis of its derivative (±)‐ 11 . Titanium(IV) chloride catalyzed cyclization of the epoxy triene (±)‐ 18 yielded the hydrobenz[ e ]indene derivative (±)‐ 19 as a mixture of stereoisomers. The structure of (±)‐ 19 was solved by X‐ray analyses of its derivatives (±)‐ 20 and (±)‐ 21 .

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