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Unexpected triphenylphosphane‐promoted conversion of 2‐azido‐3‐vinyl‐l, 4‐naphthoquinones into 2‐amino‐3‐acyl‐l, 4‐naphthoquinones
Author(s) -
Molina Pedro,
Tárraga Alberto,
Baño Maria Jose Del,
Espinosa Arturo
Publication year - 1994
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199419940220
Subject(s) - chemistry , stereochemistry , organic chemistry , combinatorial chemistry
An unusual behavior of several 2‐azido‐3‐vinyl‐l, 4‐naphtho‐quinones 1 towards triphenylphosphane leading both to azido group reduction and unsaturated carbon‐carbon side chain oxidation is described.