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Marine Bakterien, VII. Enzymatische Bromierung von Pseudilinen und verwandten Heteroarylphenolen mit der Chlorperoxidase aus Streptomyces aureofacens Tü 24
Author(s) -
Laatsch Hartmut,
Pudleiner Heinz,
Pelizaeus Birgit,
van Pée KarlHeinz
Publication year - 1994
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199419940112
Subject(s) - streptomyces aureofaciens , chemistry , streptomyces , halogenation , stereochemistry , organic chemistry , bacteria , biology , genetics
Marine Bacteria, VII. – Enzymatic Bromination of Pseudilins and Related Heteroarylphenols with a Chloroperoxidase from Streptomyces aureofaciens Tü 24 During the bromination of various substituted synthetic phenyl pyrroles with a chloroperoxidase from Streptomyces aureofaciens Tü 24, mixtures of bromopyrroles are obtained which are not easily accessible by chemical methods. According to the structure of the pyrroles and the kinetics of their transformation, the reaction centre of the enzyme is situated in a slitlike cavity of about 4 × 7 × 8 Ä.