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Synthesis of (3 R ,25 R )‐3,25‐dihydroxyhexacosyl α‐ D ‐glucopyranoside, the heterocyst glycolipid of the marine cyanobacterium Nodularia harveyana
Author(s) -
Mori Kenji,
Qian ZhaoHui
Publication year - 1994
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199419940108
Subject(s) - heterocyst , cyanobacteria , glycolipid , chemistry , botany , biochemistry , biology , bacteria , anabaena , genetics
(3 R ,25 R )‐3,25‐Dihydroxyhexacosyl α‐ D ‐glucopyranoside ( 1a ), the heterocyst glycolipid of Nodularia harveyana , was synthesized by starting from D ‐glucose, ( S )‐malic acid ( 4 ), 1‐octadecyne ( 5 ) and ethyl ( R )‐3‐hydroxybutanoate ( 6 ).
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