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Synthesis of 6‐Deoxy and 3,6‐Dideoxy Derivatives from Unprotected Glycosides Employing the Mitsunobu Reaction
Author(s) -
Dancy Isabelle,
Laupichler Lothar,
Rollin Patrick,
Thiem Joachim
Publication year - 1993
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199319930158
Subject(s) - mitsunobu reaction , chemistry , regioselectivity , flue gas desulfurization , glycoside , combinatorial chemistry , organic chemistry , stereochemistry , catalysis
Abstract Starting with unprotected hexopyranoside derivatives, an efficient synthesis of 6‐deoxy‐ and 3,6‐dideoxyhexopyranosides was achieved in two consecutive steps involving a highly regioselective Mitsunobu reaction and subsequent desulfurization.