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Chirale Porphyrine mit C ‐verknüpften Menthyl‐Resten
Author(s) -
Marx Thomas,
Breitmaier Eberhard
Publication year - 1992
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199219920134
Subject(s) - chemistry , pyrrole , menthol , stereochemistry , styrene , medicinal chemistry , organic chemistry , copolymer , polymer
Chiral Porphyrins with C ‐Connected Menthyl Residues Chiral porphyrins 9 and 10 with C ‐connected (—)‐menthyl residues are prepared starting from (—)‐menthol 1 in eight steps, finally involving cyclization of 3‐formyl‐β‐( p ‐menth‐3‐yl)styrene ( 6 ) with pyrrole ( 7 ) or the 2,2′‐dipyrrylmethane 8 .