Premium
Polycyclic Aromatic Alkaloids, 8. The Structure of Neocalliactine Acetate — Proof by Total Synthesis
Author(s) -
Bracher Franz
Publication year - 1992
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.1992199201199
Subject(s) - chemistry , total synthesis , organic chemistry , stereochemistry
The pentacyclic compound 1 is prepared in six steps by starting from 5,8‐quinolinedione ( 7 ). Its spectral data are in accordance with those of neocalliactine acetate, a derivative or the marine alkaloid calliactine. This represents the first definite confirmation of the structure of neocalliactine acetate.