Zur stereoselektiven Synthese von 2‐ O ‐Benzyl‐1‐ O ‐hexadecyl‐ sn ‐glycerol | Zendy

Bauer Friederike | Zendy; Rueß KlausPeter | Zendy; Liefländer Manfred | Zendy

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Zur stereoselektiven Synthese von 2‐ O ‐Benzyl‐1‐ O ‐hexadecyl‐ sn ‐glycerol

Author(s) -

Bauer Friederike,

Rueß KlausPeter,

Liefländer Manfred

Publication year - 1992

Publication title -

liebigs annalen der chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0170-2041

DOI - 10.1002/jlac.199219920110

Subject(s) - chemistry , glycerol , ether , alkyl , yield (engineering) , medicinal chemistry , organic chemistry , metallurgy , materials science

Stereoselective Synthesis of 2‐ O ‐Benzyl‐1‐ O ‐hexadecyl‐ sn ‐glycerol Due to the versatility of 2‐ O ‐benzyl‐1‐ O ‐hexadecyl‐ sn ‐glycerol ( 7 ) as building block for various alkyl ether lipids and alkyl ether lyso ‐lipids, 7 was prepared from D ‐mannit following two different strategies. The final product 7 was obtained either via the intermediate 1,2‐ O ‐isopropylidene‐ sn ‐glycerol ( 1 ) or via 3,4‐ O ‐isopropylidene‐ D ‐mannit ( 8 ) in an overall yield of 6% or 11%, respectively.

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