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En Route to Thromboxane Compounds from Carbohydrates, II. Halolactonization of 4‐ c ‐Branched Alkyl Hex‐2‐enopyranosides
Author(s) -
Pelyvás István F.,
Lindhorst Thisbe K.,
Batta Gyula,
Thiem Joachim
Publication year - 1992
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199219920108
Subject(s) - chemistry , alkyl , stereochemistry , organic chemistry , medicinal chemistry
Bromolactonization of alkyl 4‐ C ‐(aminocarbonylmethyl)hex‐2‐enopyranosides 1a and 4a in nonaqueous medium results in an unexpected α‐bromination in the C‐4 side chain.