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1 H‐NMR spectra of all diastereomeric nitroalditols with a chain length up to C 7 , obtained from aldoses by the Fischer‐Sowden reaction
Author(s) -
Köll Peter,
Brandenburg Heinz,
Seelhorst Willi,
Stenns Claudia,
Kogelberg Heide
Publication year - 1991
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199119910137
Subject(s) - diastereomer , chemistry , nmr spectra database , spectral line , nitro , group (periodic table) , carbon 13 nmr , carbon fibers , carbon chain , crystallography , stereochemistry , organic chemistry , materials science , composite number , composite material , physics , alkyl , astronomy
The 1 H‐NMR spectra of all diastereomeric alditols with a terminal nitro group up to a chain length of seven carbon atoms (31 compounds) have been recorded at 500 MHz in D 2 O. In most cases, a complete first‐order analysis has been performed. The spectra show systematic correlations with those of the parent alditols. Despite a special situation around the nitromethyl group no severe deviations of preferred conformations in solution from those of the parent alditols have been observed.