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Pheromone synthesis, CXXXI. Synthesis of the four stereoisomers of 6,10,13‐trimethyl‐1‐tetradecanol, the aggregation pheromone of predatory stink bug, Stiretrus anchorago
Author(s) -
Mori Kenji,
Wu Jiang
Publication year - 1991
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.1991199101134
Subject(s) - pheromone , chemistry , citronellol , stereochemistry , botany , geraniol , biology , food science , essential oil
The synthesis of the four stereoisomers of 6,10,13‐trimethyl‐1‐tetradecanol ( 1a ), the male‐produced aggregation pheromone of the predatory stink bug Stiretrus anchorago , was achieved by starting from ( R )‐citronellol ( 2a ), methyl ( R )‐ or ( S )‐3‐hydroxy‐2‐methylpropanoate ( 10 ) and 4‐chloro‐1‐butanol ( 12a ).