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Bonellin: Aufklärung der absoluten Konfiguration
Author(s) -
Montforts FranzPeter,
Müller Claudia Margrit,
Lincke Anngret
Publication year - 1990
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199019900180
Subject(s) - chemistry , absolute configuration , ozonolysis , stereochemistry , organic chemistry
Bonellin: Determination of Its Absolute Configuration The absolute configuration of bonellin ( 3 ), the physiologically active pigment of the marine echiuroid worm Bonellia viridis , has been established as ( S ) by ozonolytic degradation. Ozonolysis forms the imide 5 the configuration of which was confirmed by CD spectroscopic comparison with 5 from degradation of vitamin B 12 .