Hydroacridine, XIII. Sterischer Verlauf der  N ‐Oxidation von  N ‐Alkyl‐Derivaten des (4aα,8aβ,9aβ,10aα)‐Tetradecahydroacridins (α‐Perhydroacridin) | Zendy

Potmischil Francisc | Zendy; Naiman Marian | Zendy

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Hydroacridine, XIII. Sterischer Verlauf der N ‐Oxidation von N ‐Alkyl‐Derivaten des (4aα,8aβ,9aβ,10aα)‐Tetradecahydroacridins (α‐Perhydroacridin)

Author(s) -

Potmischil Francisc,

Naiman Marian

Publication year - 1990

Publication title -

liebigs annalen der chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0170-2041

DOI - 10.1002/jlac.199019900114

Subject(s) - chemistry , steric effects , alkyl , medicinal chemistry , yield (engineering) , oxygen , hydrogen peroxide , nitrogen , peroxide , nitrogen atom , stereochemistry , organic chemistry , materials science , metallurgy

Hydroacridines, XIII. — Steric Course of the N ‐Oxidation of N ‐Alkyl Derivatives of ((4aα,8aβ,9aβ,10aα)‐Tetradecahydroacridine (α‐Perhydroacridine) Diese Arbeit wurde auf der 5. rumänischen Konferenz für allgemeine und angewandte physikalische Chemie, Bukarest, 1. −4. September 1976, mitgeteilt. The oxidation of N ‐methyl‐α‐perhydroacridine ( 1 ), with hydrogen peroxide at room temperature occurs approximately with 83% by equatorial, and approximately with 17% by axial attack of the oxygen on the nitrogen atom. The oxidations of N ‐ethyl‐ ( 2 ) and N ‐benzyl‐α‐perhydroacridine ( 3 ) yield only the N ‐oxides with axial oxygen ( 2 ′ a and 3 ′ a , respectively).

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