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Solvolysis of N ‐(Chlorosulfinyl)diarylketimines
Author(s) -
AlTalib Mahmoud,
Tashtoush Hasan
Publication year - 1990
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.1990199001114
Subject(s) - chemistry , thiophenol , solvolysis , phenols , organic chemistry , ammonium , phenol , medicinal chemistry , hydrolysis
N ‐(Chlorosulfinyl)diarylketimines 1a – c readily react with alcohols, phenols and thiophenol to give good yields of dialkyl sulfites, diaryl sulfites and dithiosulfites, respectively, besides (diarylmethylene)ammonium chlorides 3a – c . The reactions of 1a with water and carboxylic acids have also been studied.