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Determination of the absolute configuration of α‐aminoalkylphosphonic acids from their CD in the presence of [Ru 2 (O 2 CC 3 H 7 ) 4 ] ⊕ Cl ⊖
Author(s) -
Frelek Jadwiga,
MajerDecker Zsuzsa,
Snatzke Günther
Publication year - 1988
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198819880318
Subject(s) - chemistry , acetonitrile , absolute configuration , analytical chemistry (journal) , absolute (philosophy) , stereochemistry , organic chemistry , philosophy , epistemology
( R )‐1‐Aminoalkylphosphonic acids show in acetonitrile/water (4:1) in the presence of the title complex intense Cotton effects around 590 (positive) and 470 nm (negative) as well as a third weaker one around 320 nm (negative).