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Reactions of rotenoids with hydroxylamine
Author(s) -
Kostova Ivanka
Publication year - 1988
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198819880302
Subject(s) - chemistry , hydroxylamine , rotenone , stereochemistry , organic chemistry , biochemistry , mitochondrion
Reaction of rotenone ( 1a ) and amorphigenin ( 2a ) with hydroxylamine in alkaline medium affords a mixture of the isoximes 5 and 6 , and the new 6a‐NH 2 spiro derivatives 12a, b and 13a, b . The structures, stereochemistry, and the mechanisms of formation of these products are discussed.