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Kaliumsuperoxid und ein neuer Weg von myo ‐ zu scyllo ‐Inositderivaten
Author(s) -
Praefcke Klaus,
Stephan Werner
Publication year - 1987
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198719870715
Subject(s) - chemistry , superoxide , derivative (finance) , potassium , nucleophile , stereochemistry , inositol , combinatorial chemistry , organic chemistry , biochemistry , catalysis , receptor , enzyme , financial economics , economics
Potassium Superoxide and a Novel Route from myo ‐ to scyllo ‐Inositol Derivatives Potassium superoxide has been used successfully as oxygen nucleophile in order to convert a myo ‐ into a scyllo ‐inositol derivative ( 1→3 ). This model reaction offers a novel and simple route to differently substituted, non ‐centrosymmetric derivatives of the rare scyllo ‐inositol starting from its commercially available myo isomer.