Synthese von Dipeptid‐triestern mit Phosphonoglycin als N‐terminaler Komponente | Zendy

Köhler Burkhard | Zendy; Schöllkopf Ulrich | Zendy

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Synthese von Dipeptid‐triestern mit Phosphonoglycin als N‐terminaler Komponente

Author(s) -

Köhler Burkhard,

Schöllkopf Ulrich

Publication year - 1987

Publication title -

liebigs annalen der chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0170-2041

DOI - 10.1002/jlac.198719870320

Subject(s) - chemistry , phosphonate , dipeptide , stereochemistry , hydrolysis , component (thermodynamics) , organic chemistry , peptide , biochemistry , thermodynamics , physics

Synthesis of Dipeptide Triesters with Phosphonoglycine as N‐terminal Component Starting with diethyl (isocyanomethyl)phosphonate ( 1 ) and methyl α‐isocyanatoalkanoates 3 a series of dipeptide triesters 5 was synthesized. As found with 5a , hydrolysis of 5 to give the dipeptides 6 with (phosphono)Gly as N‐terminal component is possible, but 6 could not be obtained in pure form.

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