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Ring‐Ketten‐ Tautomerie von 2‐Desoxy‐ D ‐ribose: Vollständige Analyse der Dynamik durch NMR‐Linienformsimulation und Spinsättigungsübertragung
Author(s) -
Bauer Hans,
Brinkmeier Arno,
Buddrus Joachim,
Jablonowski Maria
Publication year - 1986
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198619861014
Subject(s) - chemistry , tautomer , ribose , spins , pyranose , furanose , stereochemistry , ring (chemistry) , crystallography , physics , organic chemistry , enzyme , condensed matter physics
Ring‐chain Tautomerism of 2‐Deoxy‐ D ‐ribose: Complete Analysis of the Dynamics by NMR Line‐shape Simulation and Spin‐saturation Transfer For the first time all rate constants assoziated with the pyranose–aldehyde–furanose equilibrium of a sugar (2‐deoxy‐ D ‐ribose) have been determined by NMR. Line‐shape analysis and spin‐saturation transfer give the same results.