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Über Synthese und Reaktionen neuer vinyloger Chlorformamidine
Author(s) -
Ried Walter,
Schöpke Klaus
Publication year - 1986
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198619860219
Subject(s) - chemistry , nucleophile , sulfur , methylene , hydrolysis , stereochemistry , medicinal chemistry , organic chemistry , catalysis
On the Synthesis and Reactions of New Vinylogous Chloroformamidines The (chloromethylene)propanedinitriles 1 and 2 react with the [bis(dialkylamino)methylene]‐propanedinitriles 3a – g to give the vinylogous chloroformamidines 4a – g and 5a , d , respectively. Hydrolysis of compound 4a leads to the product 6 . Treatment of 4a with the sulfur nucleophiles 12a – e , 11a – c , 8 , and 9 results in the compounds 14a – e , 13a – c , 7 , and 10 .