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3α,13‐Dihydroxyforesaconitin aus den Wurzeln von Aconitum forestii Stapf
Author(s) -
WeiShin Chen,
SepulvedaBoza Silvia,
Mörtter Monika,
Breitmaier Eberhard
Publication year - 1985
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198519850621
Subject(s) - aconitum , chemistry , proton , botany , stereochemistry , alkaloid , physics , biology , quantum mechanics
3α,13‐Dihydroxyforesaconitine from the Roots of Aconitum forestii Stapf 3α,13‐Dihydroxyforesaconitine ( 1 ) was isolated from the roots of Aconitum forestii Stapf. It was identified as the 8‐ O ‐acetyl‐14‐ O ‐(4‐methoxybenzoyl) derivate of 3α,8β,13,14α‐tetrahydroxy‐1α,6α,16β‐trimethoxy‐4β‐(methoxymethyl)aconitane ( 2 ). Substructures of 2 obtained by hydrolysis of 1 were derived from two‐dimensional carbon‐proton and proton‐proton shift correlations.