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Synthesen mit α‐metallierten Isocyaniden, LIII. Synthese von 2,3‐Epoxy‐2‐isocyanalkansäure‐methylestern
Author(s) -
Hoppe Inga,
Schöllkopf Ulrich
Publication year - 1984
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198419840318
Subject(s) - chemistry , sodium methoxide , sodium hydroxide , methanol , epoxy , methoxide , medicinal chemistry , nuclear chemistry , stereochemistry , organic chemistry
Syntheses with α‐Metalated Isocyanides, LIII. — Synthesis of Methyl 2,3‐Epoxy‐2‐isocyanoalkanoates The title compounds were synthesized from methyl α‐isocyanoacrylates 2 with H 2 O 2 (in sodium hydroxide solution) or with m ‐chloroperbenzoic acid (in methanol/sodium methoxide)