Cyclit‐Reaktionen, IX. Synthese von 1 L ‐1‐Desoxy‐1‐ C ‐hydroxymethyl‐ myo ‐inosit und 1 L ‐1‐Desoxy‐1‐ C ‐hydroxymethyl‐ chiro ‐inosit | Zendy

Paulsen Hans | Zendy; Röben Wolfgang | Zendy

Premium

Cyclit‐Reaktionen, IX. Synthese von 1 L ‐1‐Desoxy‐1‐ C ‐hydroxymethyl‐ myo ‐inosit und 1 L ‐1‐Desoxy‐1‐ C ‐hydroxymethyl‐ chiro ‐inosit

Author(s) -

Paulsen Hans,

Röben Wolfgang

Publication year - 1983

Publication title -

liebigs annalen der chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 0170-2041

DOI - 10.1002/jlac.198319830618

Subject(s) - chemistry , hydroxymethyl , cyclitol , stereochemistry , methylene , inositol , medicinal chemistry , biochemistry , receptor

Cyclitol Reactions, IX. – Synthesis of 1 L ‐1‐Deoxy‐1‐ C ‐hydroxymethyl‐ myo ‐inositol and 1 L ‐1‐Deoxy‐1‐ C ‐hydroxymethyl‐ chiro ‐inositol Hydroboration of the exo ‐methylene compound 3 with disiamylborane leads to the alcohols 4 and 6 . Removal of the protective groups results in the enantiomerically pure, branched‐chain (hydroxymethyl)inositols having 1 L ‐ myo configuration and 1 L ‐ chiro configuration, respectively.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research