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1,1‐Diphenyl‐2‐azaalleniumionen als Intermediärprodukte
Author(s) -
Böhme Horst,
Braun Günther,
Ingendoh Axel
Publication year - 1983
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198319830423
Subject(s) - chemistry , sodium iodide , acetonitrile , iodide , sodium , trimethylamine , cyanide , ion , cyanide ion , sodium cyanide , medicinal chemistry , organic chemistry
1,1‐Diphenyl‐2‐azaallenium Ions as Intermediates Under elimination of trimethylamine and formation of 1,1‐diphenyl‐2‐azaallenium ion intermediates 2d from [(diphenylmethylene)aminomethyl]trimethylammonium iodide ( 5 ) on heating with sodium methanolate the N ‐(diphenylmethylene)methoxymethylamine ( 6 ) is obtained. With sodium methanethiolate the N ‐(diphenylmethylene)methylthiomethylamine ( 7 ), with sodium cyanide the [(diphenylmethylene)amino]acetonitrile ( 8 ) are formed.