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Regioselektive Synthesen von 3,3′‐Bijuglon, Mamegakinon, Dianellinon, cyclo ‐Trijuglon, Xylospyrin und Trianellinon durch Phenol/Chinon‐Addition
Author(s) -
Brockmann Hans,
Laatsch Hartmut
Publication year - 1983
Publication title -
liebigs annalen der chemie
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198319830310
Subject(s) - chemistry , phenol , medicinal chemistry , stereochemistry , organic chemistry
Durch regioselektive Phenol/Chinon‐Addition werden aus Juglon ( 1a ), 7‐Methyljuglon ( 1b ) und Stypandron ( 1c ) in Pyridin die Dimeren 3,3′‐Bijuglon ( 5a ), Mamegakinon ( 5c ), Dianellinon ( 5e ) und in Eisessig die cyclo‐Trimeren cyclo‐Trijuglon ( 12a ), Xylospyrin ( 12d ) und Trianellinon ( 12g ) synthetisiert.
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