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Versuche zur Reduktion des Dichlormethandisulfonyldichlorids
Author(s) -
Senning Alexander
Publication year - 1981
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198119811119
Subject(s) - chemistry , morpholine , methanol , medicinal chemistry , organic chemistry
Experiments Concerning the Reduction of Dichloromethanedisulfonyl Dichloride Mild reducing agents, including methanol, reduce dichloromethanedisulfonyl dichloride ( 2 ) to give dichloro(chlorosulfonyl)methanesulfinic acid ( 6 ) which desulfinylates spontaneously to form dichloromethanesulfonyl chloride ( 9 ). Chloromethanedisulfonyl dichloride ( 12 ) ist not reduced under these conditions and can be derivatized „normally”, for instance with morpholine.