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Brewery spent grain: a potential biosorbent for hexavalent chromium
Author(s) -
Vendruscolo Francielo,
Reis Carolina Leandra Fantt de Sousa e,
Silva Jessica Guimarães
Publication year - 2021
Publication title -
journal of the institute of brewing
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.523
H-Index - 51
eISSN - 2050-0416
pISSN - 0046-9750
DOI - 10.1002/jib.638
Subject(s) - hexavalent chromium , chromium , chemistry , metallurgy , environmental chemistry , pulp and paper industry , waste management , food science , materials science , engineering
Spent grain is a solid waste from the brewery process which is used as feed for ruminants or as organic fertiliser. Due to the large scale generation of spent grain, new technological and industrial applications are being developed. In this work, spent grain was modified by chemical treatments for use in the biosorption of hexavalent chromium. For spent grain treated with acid, alkali, petroleum ether and hydrogen peroxide, the amount of hexavalent chromium removed was respectively 97, 21, 0.9 and 0.5%. The kinetic data of spent grain biosorbent treated with acid, untreated and treated with alkali were applied to pseudo‐first order, pseudo‐second order and intraparticle diffusion models. The pseudo‐second order model showed the best fit to the kinetic data, indicating chemisorption in the biosorption processes. The effects of pH and biosorbent concentration were analysed for spent grain treated with acid. The optimum values for pH and concentration of the biosorbent were pH 2 and 2 g/L.