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2,2‐Bis(methoxy‐ NNO ‐azoxy)ethyl Derivatives of 4,8‐Dihydro‐bis‐furazano[3,4‐ b :3′4′‐ e ]pyrazine: The Synthesis and X‐ray Investigation
Author(s) -
Zyuzin Igor N.,
Suponitsky Kyrill Yu.,
Sheremetev Aleksei B.
Publication year - 2012
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.811
Subject(s) - azoxy , chemistry , pyrazine , medicinal chemistry , ethanol , stereochemistry , organic chemistry
The first synthesis of 4,8‐dihydro‐bis‐furazano[3,4‐ b :3′4′‐ e ]pyrazine bearing 2,2‐bis(methoxy‐ NNO ‐azoxy)ethyl groups has been developed. These compounds are obtained by aza‐Michael reaction of 1,1‐bis(methoxy‐ NNO‐ azoxy)ethene or its equivalents, such as 2,2‐bis(methoxy‐ NNO‐ azoxy)ethanol derivatives, with 4,8‐dihydro‐bis‐furazano[3,4‐ b :3′4′‐ e ]pyrazine.