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Microwave‐assisted synthesis, metallation, and duff formylation of porphyrins
Author(s) -
Yaseen Muhammad,
Ali Mukhtar,
NajeebUllah Muhammad,
Ali Munawar Munawar,
Khokhar Irshad
Publication year - 2009
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.78
Subject(s) - formylation , chemistry , microwave , elemental analysis , mass spectrometry , organic chemistry , microwave chemistry , photochemistry , combinatorial chemistry , catalysis , microwave irradiation , chromatography , physics , quantum mechanics
Microwave assisted synthesis, metallation, and β‐formylation of porphyrins is described. All synthetic reactions were carried out on inorganic polymer solid support using microwave energy. It is the first documented application of the Duff reaction in the field of porphyrins and metalloporphyrins. The overall process is simple, easy, and environment friendly. FTIR, UV–visible, elemental analysis, 1 H NMR, and mass spectrometry were used to characterize the compounds. J. Heterocyclic Chem., 46 , 251 (2009).