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Macrocyclic compounds from benzenedithiols and triazine: Modification of tetrathiacalix[4]arene
Author(s) -
Alam Ashraful,
Yamaguchi Miharu,
Yamamoto Tatsuya,
Nakajo Shiduko,
Ogawa Satoshi,
Sato Ryu
Publication year - 2008
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570450225
Subject(s) - chemistry , triazine , sulfur , solid state , combinatorial chemistry , stereochemistry , 1,3,5 triazine , polymer chemistry , computational chemistry , crystallography , organic chemistry
ynthesis of macrocyclic compounds having benzenedithionate and triazine moieties was achieved by an efficient fragment coupling approach. In the solid state, they adopted 1,3 ‐alternate conformations. Combination of two pairs of electron rich and electron poor units, and ortho‐ortho and/or ortho‐meta connections of sulfur atoms with aromatic carbons were novel features of the macrocycles.